Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/5222
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dc.contributor.authorGonsalves, António M. d'A. Rocha-
dc.contributor.authorSerra, Arménio C.-
dc.date.accessioned2008-09-01T15:06:02Z-
dc.date.available2008-09-01T15:06:02Z-
dc.date.issued2001en_US
dc.identifier.citationJournal of Molecular Catalysis A: Chemical. 168:1-2 (2001) 25-32en_US
dc.identifier.urihttp://hdl.handle.net/10316/5222-
dc.description.abstractThe role of the carboxylic acid as co-catalyst in metalloporphyrin catalytic hydrogen peroxide oxidations is discussed, taking into account its dependence on the ratio relatively to the catalyst. The catalytic efficiency and stability of the catalyst in the presence of an excess of carboxylic acid suggests that a metallo-acylperoxo complex can be the effective oxidation intermediate.en_US
dc.description.urihttp://www.sciencedirect.com/science/article/B6TGM-42G6XGY-4/1/0ef5cfc94471f6985d77385ef339282ben_US
dc.format.mimetypeaplication/PDFen
dc.language.isoengeng
dc.rightsopenAccesseng
dc.subjectMetalloporphyrinen_US
dc.subjectCatalysisen_US
dc.subjectHydrogen peroxideen_US
dc.subjectOxidationen_US
dc.titleOn the mechanism of carboxylic acid co-catalyst assisted metalloporphyrin oxidationsen_US
dc.typearticleen_US
item.fulltextCom Texto completo-
item.languageiso639-1en-
item.grantfulltextopen-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.researchunitCentre for Mechanical Engineering-
crisitem.author.orcid0000-0001-9987-7301-
crisitem.author.orcid0000-0001-8664-2757-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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