Please use this identifier to cite or link to this item:
Title: Synthesis, crystal structure and magnetic properties of an alternating manganese chain
Authors: Silva, Manuela Ramos 
Beja, Ana Matos 
Paixão, José António 
Martín-Gil, Jesus 
Keywords: Mn(ii) complexes; Dimethylglycine; X-ray structure; Antiferromagnetic interaction
Issue Date: 2006
Citation: Journal of Solid State Chemistry. 179:7 (2006) 2054-2058
Abstract: A new 1D complex has been prepared and characterized. X-ray single crystal structure confirms that the Mn(II) ions assemble in alternating chains with Mn-Mn distances of 3.8432(13) and 4.4428(14) Å. A 3D network of hydrogen bonds links the chains together. The temperature dependence of the magnetic susceptibility reveals that this compound undergoes a magnetic transition and exhibits an antiferromagnetic interaction in the low-temperature phase with two alternating exchange interactions of -2.32(1) and -5.55(1) cm-1.
Rights: openAccess
Appears in Collections:FCTUC Física - Artigos em Revistas Internacionais

Files in This Item:
File Description SizeFormat
filec33a231400d54128bc22074b24be29d5.pdf328.97 kBAdobe PDFView/Open
Show full item record

Page view(s)

checked on Jul 8, 2020


checked on Jul 8, 2020

Google ScholarTM


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.