Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/10315
DC FieldValueLanguage
dc.contributor.authorPais, A. A. C. C.-
dc.contributor.authorVoronin, A. I.-
dc.contributor.authorVarandas, A. J. C.-
dc.date.accessioned2009-06-24T14:26:12Z-
dc.date.available2009-06-24T14:26:12Z-
dc.date.issued1996-05-02-
dc.identifier.citationhe Journal of Physical Chemistry. 100:18 (1996) 7480-7487en_US
dc.identifier.urihttp://hdl.handle.net/10316/10315-
dc.description.abstractBy using the accurate DMBE III potential energy surface for Li3, we have carried out a detailed dynamics study of the title reaction. Besides reporting on the effect of translational and vibrational excitation of the reactants, a comparison is also presented for two models for defining the collision complex. The results support the coexistence of two different types of reaction mechanisms. One, characterized by long-lived trajectories, dominates at low-energy regimes and vibrational excitation. The other, mostly associated with direct type trajectories, starts to play a more important role at still reasonably low collisional energies, depending on the vibrational state of the reactants. It is also shown that, for initial vibrational excitation of diatomic, short-lived collision complexes can be associated with extensive randomization of vibrational energy.en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsopenAccesseng
dc.titleDynamics of the Li + Li2 Reaction: Coexistence of Statistical and Direct Attributesen_US
dc.typearticleen_US
dc.identifier.doi10.1021/jp9530818-
item.fulltextCom Texto completo-
item.languageiso639-1en-
item.grantfulltextopen-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.orcid0000-0002-6725-6460-
crisitem.author.orcid0000-0003-1501-3317-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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