Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/10314
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dc.contributor.authorMarques, J. M. C.-
dc.contributor.authorWang, W.-
dc.contributor.authorPais, A. A. C. C.-
dc.contributor.authorVarandas, A. J. C.-
dc.date.accessioned2009-06-24T14:20:40Z-
dc.date.available2009-06-24T14:20:40Z-
dc.date.issued1996-10-31-
dc.identifier.citationThe Journal of Physical Chemistry. 100:44 (1996) 17513-17522en_US
dc.identifier.urihttp://hdl.handle.net/10316/10314-
dc.description.abstractTrajectory calculations have been carried out for the title reaction over the range of translational energies 0.25 ≤ Etr/kcal mol-1 ≤ 131.4. We present reactive cross sections for formation of stable HO2 for translational energies up to 8.0 kcal mol-1, while for O2 formation the reported cross sections extend over the whole range of translational energies. The former cross sections are shown to decrease with increasing translational energy, while the latter cross sections show a slight increase leading to a broad maximum and finally approach zero at high energies. Similarly, the formation of OH products has been investigated in detail and compared with the corresponding process in the absence of argon. Formation and dissociation of energized HO2* complexes have also been analyzed and the decay rates rationalized by means of a simple two-step kinetic mechanism.en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsopenAccesseng
dc.titleDynamics Study of the H + ArO2 Multichannel Reactionen_US
dc.typearticleen_US
dc.identifier.doi10.1021/jp961863a-
item.fulltextCom Texto completo-
item.grantfulltextopen-
item.languageiso639-1en-
crisitem.author.deptFaculty of Sciences and Technology-
crisitem.author.deptFaculty of Sciences and Technology-
crisitem.author.deptFaculty of Sciences and Technology-
crisitem.author.parentdeptUniversity of Coimbra-
crisitem.author.parentdeptUniversity of Coimbra-
crisitem.author.parentdeptUniversity of Coimbra-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0002-8124-3156-
crisitem.author.orcid0000-0002-6725-6460-
crisitem.author.orcid0000-0003-1501-3317-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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