Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/10060
Title: Synthesis and structure of novel benzisothiazole-tetrazolyl derivatives for potential application as nitrogen ligands
Authors: Frija, Luís M. T. 
Fausto, R. 
Loureiro, Rui M. S. 
Cristiano, M. Lurdes S. 
Keywords: Benzisothiazole; Tetrazole; Nitrogen ligands
Issue Date: 2009
Citation: Journal of Molecular Catalysis A: Chemical. In Press, Corrected Proof:
Serial title, monograph or event: Journal of Molecular Catalysis A: Chemical
Volume: 305
Abstract: The synthesis and characterization of novel benzisothiazole-tetrazolyl derivatives differing on the spacer-group used for the linkage of two heterocycles are described. The application of these compounds as nitrogen ligands for coordination with transition metals was also explored, leading to the preparation of 3-[1-(2-1H-tetrazol-5-yl)ethoxy]-1,2-benzisothiazole 1,1-dioxide-Mn(II) and N-(1,1-dioxo-1,2-benzisothiazol-3-yl)-amine-1H-tetrazole-Mn(II) complexes. Graphical abstract Novel benzisothiazole-tetrazolyl derivatives, differing on the spacer-group used for linkage of the two heterocycles, were devised. The application of these compounds as nitrogen ligands for coordination with transition metals was also explored.
URI: http://hdl.handle.net/10316/10060
DOI: 10.1016/j.molcata.2008.12.007
Rights: openAccess
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais

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